第十四章 红外分光光度法
红外线:infrared ray,IR
中红外吸收光谱:mid-infrared absorption spectrum,Mid-IR
远红外光谱:Far-IR
微波谱:microwave spectrum,MV
红外吸收光谱法:infrared spectroscopy
红外分光光度法:infrared spectrophotometry
振动形式:mode of vibration
伸缩振动:stretching vibration
对称伸缩振动:symmetrical stretching vibration
不对称伸缩振动:asymmetrical stretching vibration
弯曲振动:bending vibration
变形振动:formation vibration
面内弯曲振动:in-plane bending vibration,β
剪式振动:scissoring vibration,δ
面内摇摆振动:rocking vibration,ρ
面外弯曲振动:out-of-plane bending vibration,γ
面外摇摆振动:wagging vibration,ω
蜷曲振动:twisting vibration ,τ
对称变形振动:symmetrical deformation vibration ,δs
不对称变形振动:asymmetrical deformation vibration, δas
特征吸收峰:charateristic avsorption band
特征频率:characteristic frequency
相关吸收峰:correlation absorption band
杂化影响:hybridization affect
环大小效应:ring size effect
吸收峰的强度:intensity of absorption band
环折叠振动:ring prckering vibration
第十五章 原子吸收分光光度法
原子光谱法:atomic spectroscopy
原子吸收分光光度法:atomic absorption spectrophotometry,AAS
原子发射分光光度法:atomic emmsion spectrophotometry,AES
原子荧光分光光度法:atomic fluorescence spectrophotometry,AFS
第十六章 核磁共振波谱法
核磁共振:nuclear magnetic resonance,NMR
核磁共振波谱:NMR spectrum
核磁共振波谱法:NMR spectroscopy
扫场:swept field
扫频:seept frequency
连续波核磁共振:continuous wave NMR,CW NMR
Fourier变换NMR:PFT-NMR,FT-NMR
二维核磁共振谱:2D-NMR
质子核磁共振谱:proton magnetic resonance spectrum,PMR
氢谱:1H-NMR
碳-13核磁共振谱:13C-NMR spectrum,13CNMR
自旋角动量:spin angular momentum
磁旋比:magnetogyric ratio
磁量子数:magnetic quantum number,m
进动:precession
弛豫历程:relaxation mechanism
局部抗磁屏蔽:local diamagnetic shielding
屏蔽常数:shielding constant
化学位移:chemical shift
国际纯粹与应用化学协会:IUPAC
磁各向异性:magnetic anisotropy
远程屏蔽效应:long range shielding effect
结面:nodal plane
自旋-自旋偶合:spin-spin coupling
自旋-自旋分裂:spin=spin splitting
单峰:singlet,s
双峰:doublet,d
三重峰:triplet,t
四重峰:quartet
五重峰:quintet
六重峰:sextet
偕偶:geminal coupling
邻偶:vicinal coupling
远程偶合:long range coupling
磁等价:magnetic eqivalence
自旋系统:spin system
一级光谱:first order spectrum
二级光谱(二级图谱):second order spectrum
C-H光谱:C-H correlated spectroscopy,C-H COSY
第十七章 质谱法
质谱分析法:mass spectrometry
质谱:mass spectrum,MS
棒图:bar graph
选择离子检测:selected ion monitoring ,SIM
直接进样:direct probe inlet ,DPI
接口:interface
气相色谱-质谱联用:gas chromatography-mass spectrometry,GC-MS
高效液相色谱-质谱联用:high performance liquid chromatography-mass spectrometry,HPLC-MS
电子轰击离子源:electron impact source,EI
离子峰:quasi-molecular ions
化学离子源:chemical ionization source,CI
场电离:field ionization,FI
场解析:field desorptiion,FD
快速原子轰击离子源:fast stom bombardment ,FAB
质量分析器:mass analyzer
磁质谱仪:magnetic-sector mass spectrometer
四极杆质谱仪(四极质谱仪):quadrupole mass spectrometer
原子质量单位:amu
离子丰度:ion abundance
相对丰度(相对强度):relative avundance
基峰:base peak
质量范围:mass range
分辨率:resolution
灵敏度:sensitivity
信噪比:S/N
分子离子:molecular ion
碎片离子:fragment ion
同位素离子:isotopic ion
亚稳离子:metastable ion
亚稳峰:metastable peak
母离子:paren ion
子离子:daughter
含奇数个电子的离子:odd electron
含偶数个电子的离子:even eletron,EE
均裂:homolytic cleavage
异裂(非均裂):heterolytic cleavage
半均裂:hemi-homolysis cleavage
重排:rearragement
分子量:MW
α-裂解:α-cleavage
第十八章 色谱分析法概论
色谱法(层析法):chromatography
固定相:stationary phase
流动相:mobile phase
超临界流体色谱法:SFC
高效毛细管电泳法:high performance capillary electroporesis,HPEC
气相色谱法:gas chromatography,GC
液相色谱法:liquid cromatography,LC
超临界流体色谱法:supercritical fluid chromatography,SFC
气-固色谱法:GSC
气-液色谱法:GLC
液-固色谱法:LSC
液-液色谱法:LLC
柱色谱法:column chromatography
填充柱:packed column
毛细管柱:capillary column
微填充柱:icrobore packed column
高效液相色谱法:high performance liquid chromatography,HPLC
平板色谱法:planar
平板色谱法:plane chromatography
纸色谱法:paper chromatography
薄层色谱法:thin layer chromatography,TLC
薄膜色谱法;thiin film chomatography
毛细管电泳法:capillary electrophoresis,CE
分配色谱法:partition chromatography
吸附色谱法:adsorpion chromaography
离子交换色谱法:ion exchange chromatography,IEC
空间排阻色谱法:steric exclusion chromatography,SEC
亲和色谱法:affinity chromatography
分配系数:distribution cofficient
狭义分配系数:partition coefficient
凝胶色谱法:gel chromatography
凝胶渗透色谱法:gel permeation chromatography,GPC
凝胶过滤色谱法:gel filtration chromatography,GFC
渗透系数:permeation coefficien;Kp
化学键合相色谱法:chemically bonded-phase chromatography
分配系数:distribution coefficient
靛菁绿:indocyanine
气相色谱-傅立叶变换红外光谱:GC-FTIR
第十九章 经典液相色谱法
薄层色谱法:TLC
吸附:adsorption
活化:activation
脱活性:deactivation
交联度:degree of cross linking
交换容量:exchange capacity